Asymmetric Formal Carbonyl-Ene Reactions of Formaldehyde tert-Butyl Hydrazone with α‑Keto Esters: Dual Activation by Bis-urea Catalysts
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https://figshare.com/articles/dataset/Asymmetric_Formal_Carbonyl_Ene_Reactions_of_Formaldehyde_i_tert_i_Butyl_Hydrazone_with_Keto_Esters_Dual_Activation_by_Bis_urea_Catalysts/2497888
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资源简介：
The dual activation of α-keto esters and formaldehyde tert-butyl hydrazone by BINAM-derived bis-ureas is the key to achieve high reactivity and excellent enantioselectivities in nucleophilic addition (formal carbonyl-ene reaction) to functionalized tertiary carbinols. Ensuing high-yielding diazene-to-aldehyde tranformations and subsequent derivatizations provides a direct entry to a variety of densely functionalized products.
创建时间：
2016-02-20
