Oxygen Transfer from an Intramolecularly Coordinated Diaryltellurium Oxide to Acetonitrile. Formation and Combined AIM and ELI‑D Analysis of a Novel Diaryltellurium Acetimidate
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https://figshare.com/articles/dataset/Oxygen_Transfer_from_an_Intramolecularly_Coordinated_Diaryltellurium_Oxide_to_Acetonitrile_Formation_and_Combined_AIM_and_ELI_D_Analysis_of_a_Novel_Diaryltellurium_Acetimidate/2267911
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The reaction of the intramolecularly coordinated diaryltellurium(IV) oxide (8-Me2NC10H6)2TeO with acetonitrile proceeds with oxygen transfer and gives rise to the formation of the novel zwitterionic diaryltelluronium(IV) acetimidate (8-Me2NC10H6)2TeNC(O)CH3 (1) in 57% yield. Hydrolysis of 1 with hydrochloric acid affords acetamide and the previously known diarylhydroxytelluronium(IV) chloride [(8-Me2NC10H6)2Te(OH)]Cl.
创建时间：
2016-02-17
