Formation of a Double-Bicapped Hexatin Phosphate Cage by a De-arylation Reaction. Synthesis and Structure of [(PhSn)<sub>6</sub>(μ-OH)<sub>2</sub>(μ<sub>3</sub>-O)<sub>2</sub>(μ-OEt)<sub>4</sub>{(ArO)PO<sub>3</sub>}<sub>4</sub>] (Ar = 2,6-<i>i-</i>Pr<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)
收藏NIAID Data Ecosystem2026-03-11 收录
数据链接：
官方服务：
资源简介：
The reaction of bis(triphenyl)tin oxide, (Ph3Sn)2O, with 2,6-diisopropylphenylphosphate, (ArO)PO3H2 (Ar = 2,6-i-Pr2-C6H3), leads to the formation of a novel double-bicapped hexanuclear monoorganooxotin cage, [(PhSn)6(μ-OH)2(μ3-O)2(μ-OEt)4{(ArO)PO3}4]. This reaction proceeds by a de-arylation reaction involving the cleavage of Sn−C bonds.
创建时间：
2007-08-27
