Deactivation of the Shvo Catalyst by Ammonia: Synthesis, Characterization, and Modeling
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https://figshare.com/articles/dataset/Deactivation_of_the_Shvo_Catalyst_by_Ammonia_Synthesis_Characterization_and_Modeling/2883391
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资源简介：
The novel stable Shvo ammonia complex [2,3,4,5-Ph4(η4-C4CO)]Ru(CO)2(NH3) (6) has been isolated in high yield in the catalytic alkylation of aniline with hexylamine. It has been characterized by X-ray analysis and density functional theory computation. The thermodynamic stability of Shvo-like ruthenium complexes with primary, secondary, and tertiary amines has been computed and compared. Calculations confirmed the high stability of this ruthenium ammonia complex.
创建时间：
2016-02-26
