Deactivation of the Shvo Catalyst by Ammonia: Synthesis, Characterization, and Modeling
收藏NIAID Data Ecosystem2026-03-06 收录
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The novel stable Shvo ammonia complex [2,3,4,5-Ph4(η4-C4CO)]Ru(CO)2(NH3) (6) has been isolated in high yield in the catalytic alkylation of aniline with hexylamine. It has been characterized by X-ray analysis and density functional theory computation. The thermodynamic stability of Shvo-like ruthenium complexes with primary, secondary, and tertiary amines has been computed and compared. Calculations confirmed the high stability of this ruthenium ammonia complex.
创建时间：
2016-02-26
