Access to Isoquinolines and Isoquinolin-3-ols via Rh(III)-Catalyzed Coupling/Cyclization Cascade Reaction of Arylimidates and Diazo Compounds
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https://figshare.com/articles/dataset/Access_to_Isoquinolines_and_Isoquinolin_3_ols_via_Rh_III_Catalyzed_Coupling_Cyclization_Cascade_Reaction_of_Arylimidates_and_Diazo_Compounds/3173287
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资源简介：
A Rh(III)-catalyzed
coupling/cyclization cascade reaction is described,
which involves arylimidates and diazo compounds and proceeds via intermolecular
C–C bond formation and subsequent intramolecular C–N
bond formation. Mechanistic investigation revealed that the reaction
is a two-step process: the initial Rh(III)-catalyzed coupling/cyclization
proceeds very fast and the following dehydration is rather slow. The
reaction provides a direct approach to isoquinolines and isoquinolin-3-ols
without any oxidants.
创建时间：
2016-05-02
