Hydrolysis of Osmium and Ruthenium Carbyne Complexes
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Hydrolysis reactions of MCl3(CCHC(ArCl)2)(PPh3)2 (M = Ru, Os) were investigated. Treatment of OsCl3(CCHC(o,o′-C6H3Cl2)2)(PPh3)2 with water produced the six-membered metallacycle OsCl(κC,κCl-CHC(o,o′-C6H3Cl2)2)(CO)(PPh3)2. Reactions of MCl3(CCHC(o-C6H4Cl)2)(PPh3)2 (M = Ru, Os) produced the related six-membered metallacycles MCl(κC,κCl-CHC(o-C6H4Cl)2)(CO)(PPh3)2.
创建时间：
2016-02-22
