Cationic Ethylzinc Compound: A Benzene Complex with Catalytic Activity in Hydroamination and Hydrosilylation Reactions
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https://figshare.com/articles/dataset/Cationic_Ethylzinc_Compound_A_Benzene_Complex_with_Catalytic_Activity_in_Hydroamination_and_Hydrosilylation_Reactions/2581744
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资源简介：
The tight ion pair [EtZn(η3-C6H6)][CHB11Cl11]·C6H6 (1·C6H6) was
obtained
through β-hydrogen abstraction and concomitant ethene elimination
from Et2Zn with the trityl salt [Ph3C][CHB11Cl11]. This ionlike species shows catalytic activity
in hydrosilylation and intramolecular hydroamination reactions. The
amine adduct {CH2CHCH2C(Ph2)CH2NH2}3ZnCB11Cl11 (3), which features a rare transition metal–carborane
σ bond, was isolated from a hydroamination experiment.
创建时间：
2011-11-21
