Materials Data on Co(RhS2)2 by Materials Project
收藏Mendeley Data2024-01-31 更新2024-06-28 收录
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https://www.osti.gov/servlets/purl/1704290/
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资源简介：
CoRh2S4 is Spinel structured and crystallizes in the cubic Fd-3m space group. The structure is three-dimensional. Rh3+ is bonded to six equivalent S2- atoms to form RhS6 octahedra that share corners with six equivalent CoS4 tetrahedra and edges with six equivalent RhS6 octahedra. All Rh–S bond lengths are 2.40 Å. Co2+ is bonded to four equivalent S2- atoms to form CoS4 tetrahedra that share corners with twelve equivalent RhS6 octahedra. The corner-sharing octahedral tilt angles are 56°. All Co–S bond lengths are 2.14 Å. S2- is bonded in a distorted rectangular see-saw-like geometry to three equivalent Rh3+ and one Co2+ atom.
创建时间：
2024-01-31
