Carbonyl Complexes of Platinum(0): Synthesis and Structure of [(Cy<sub>3</sub>P)<sub>2</sub>Pt(CO)] and [(Cy<sub>3</sub>P)<sub>2</sub>Pt(CO)<sub>2</sub>]
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The platinum(0) monocarbonyl complex, [(Cy3P)2Pt(CO)], was synthesized by reaction of [(Cy3P)2Pt] with [(η5-C5Me5)Ir(CO)2] and subsequent irradiation. X-ray structure analysis was performed and represents the first structural evidence of a platinum(0) monocarbonyl complex bearing two free phosphine ligands. Its corresponding dicarbonyl complex [(Cy3P)2Pt(CO)2] was synthesized by treatment of [(Cy3P)2Pt] with CO at −40 °C and confirmed by X-ray structure analysis.
创建时间:
2011-03-07



