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Heterocyclized Carbometalation of Alkynes: Unexpected Formation of Eight-Membered Oxazirconacycles with an Intramolecularly Coordinated Isoquinoline Moiety

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Heterocyclized_Carbometalation_of_Alkynes_Unexpected_Formation_of_Eight_Membered_Oxazirconacycles_with_an_Intramolecularly_Coordinated_Isoquinoline_Moiety/3313333
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The isoquinolyl-zirconation of various unactivated alkynes was investigated by a one-pot, three-component reaction of two different alkynes with a nitrile in the presence of 1 equiv of CuCl. The true nature of the resulting products of novel eight-membered oxazirconacycles containing an intramolecular Zr−N coordination was established using X-ray crystallography.
创建时间:
2016-05-06
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