An Unprecedented Oxidative Migration of a Methyl Group from 2-(2‘,6‘-Dimethylphenylazo)-4-methylphenol Mediated by Ruthenium and Osmium
收藏NIAID Data Ecosystem2026-03-06 收录
下载链接:
https://figshare.com/articles/dataset/An_Unprecedented_Oxidative_Migration_of_a_Methyl_Group_from_2_2_6_Dimethylphenylazo_4_methylphenol_Mediated_by_Ruthenium_and_Osmium/3359593
下载链接
链接失效反馈官方服务:
资源简介:
An unprecedented chemical transformation of 2-(2‘,6‘-dimethylphenylazo)-4-methylphenol has been observed upon its reaction with
[M(PPh3)3X2] (M = Ru, Os; X = Cl, Br) whereby one methyl group
from the phenyl ring of the arylazo fragment migrates to the metal
center via oxidation to CO.
创建时间:
2003-11-17



