Regioselective Electrophilic Access to Naphtho[1,2‑<i>b</i>:8,7‑<i>b</i>′]- and -[1,2‑<i>b</i>:5,6‑<i>b</i>′]dithiophenes

A two-step one purification access to dichloronaphtho­[1,2-b:8,7-b′] and [1,2-b:5,6-b′]­dithiophenes using bis-alkylnaphthyl alkynes and phthalimidesulfenyl chloride as starting materials has been developed. The functionalization of the carbon–chlorine bonds allowed further modification of NDT core, broadening the potential of the methodology.