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Synthesis of 2,3-Benzodiazepines via Rh(III)-Catalyzed C–H Functionalization of N‑Boc Hydrazones with Diazoketoesters

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Figshare2017-06-22 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Synthesis_of_2_3-Benzodiazepines_via_Rh_III_-Catalyzed_C_H_Functionalization_of_i_N_i_Boc_Hydrazones_with_Diazoketoesters/5135587
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An efficient Rh­(III)-catalyzed C–H activation protocol has been developed for the synthesis of 2,3-benzodiazepines with use of N-Boc hydrazones and diazoketoesters as substrates. The reaction features retention of the CN and N–N bonds and selective cleavage of the N-Boc moiety.
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2017-06-22
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