Preparation of LGe(Se)OH: A Germanium Analogue of a Selenocarboxylic Acid (L = HC[(CMe)(NAr)]<sub>2</sub>, Ar = 2,6-<i>i</i>Pr<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)
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LGe(Se)OH (2) (L = HC[(CMe)(NAr)]2, Ar = 2,6-iPr2C6H3) was obtained by oxidative addition of red selenium to LGeOH (1). Compound 2 was characterized by IR, multinuclear NMR, EI-MS, and single-crystal X-ray diffraction. Furthermore, theoretical calculations of the acid strength (pKa) of compound 2 and LGe(S)OH were carried out by means of density functional theory (DFT).
创建时间：
2016-05-05
