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Synthesis of a Dinuclear Ferrocene-Linked Bis(phosphinoamide)scandium Hydride Complex

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NIAID Data Ecosystem2026-03-07 收录
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The ferrocene-based bis­(phosphinoamide) fc­(NHPiPr2)2 (where fc = 1,1′-ferrocenyl) has been synthesized and coordinated to scandium via alkane elimination. The subsequent reaction of fc­(NPiPr2)2ScCH2SiMe3(THF) with H2 yields a dinuclear scandium hydride species wherein the scandium centers are bridged by both hydride and phosphinoamide fragments.

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2016-02-18
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