Enantioselective Copper-Catalyzed Arylation-Driven Semipinacol Rearrangement of Tertiary Allylic Alcohols with Diaryliodonium Salts
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https://figshare.com/articles/dataset/Enantioselective_Copper-Catalyzed_Arylation-Driven_Semipinacol_Rearrangement_of_Tertiary_Allylic_Alcohols_with_Diaryliodonium_Salts/5160577
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资源简介：
A copper-catalyzed
enantioselective arylative semipinacol rearrangement
of allylic alcohols using diaryliodonium salts is reported. Chiral
Cu(II)-bisoxazoline catalysts initiate an electrophilic alkene arylation,
triggering a 1,2-alkyl migration to afford a range of nonracemic spirocyclic
ketones with high yields, diastereo- and enantioselectivities.
创建时间：
2017-06-29
