Contrasting Magnetism of [Mn<sup>III</sup><sub>4</sub>] and [Mn<sup>II</sup><sub>2</sub>Mn<sup>III</sup><sub>2</sub>] Squares
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Two tetranuclear manganese distorted square-shaped clusters, [MnIII4(L1)4(μ2-OMe)4]·2.5H2O (1) and [MnII2MnIII2(L2)4(H2O)2](PF6)2·CHCl3·CH3OH·1.5H2O (2) (H2L1 = 2-[3-(2-hydroxyphenyl)-1H-pyrazol-5-yl]-6-pyridinecarboxylic acid methyl ester; H2L2 = 2-[3-(2-hydroxyphenyl)-1H-pyrazol-5-yl]-6-pyridinecarboxylic acid ethyl ester), exhibit antiferromagnetic and ferromagnetic interactions between neighboring manganese ions, respectively.
创建时间：
2010-01-18
