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Potassium Thiocyanate as Source of Cyanide for the Oxidative α‑Cyanation of Tertiary Amines

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NIAID Data Ecosystem2026-03-08 收录
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https://figshare.com/articles/dataset/Potassium_Thiocyanate_as_Source_of_Cyanide_for_the_Oxidative_Cyanation_of_Tertiary_Amines/2189182
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Oxidation at the sulfur of the safe-to-handle potassium thiocyanate releases cyanide units that are trapped in the presence of co-oxidized tertiary amines to form α-amino nitriles. These cyanations work in aqueous solutions and do not require a catalyst, nor do they form toxic byproducts.
创建时间:
2016-02-14
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