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Investigating the Dearomative Rearrangement of Biaryl Phosphine-Ligated Pd(II) Complexes

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NIAID Data Ecosystem2026-03-09 收录
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A series of monoligated L·PdII(Ar)­X complexes (L = dialkyl biaryl phosphine) have been prepared and studied in an effort to better understand an unusual dearomative rearrangement previously documented in these systems. Experimental and theoretical evidence suggest a concerted process involving the unprecedented PdII-mediated insertion of an aryl group into an unactivated arene.

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2016-02-20
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