An Isolable Silanoic Ester by Oxygenation of a Stable Silylene
收藏NIAID Data Ecosystem2026-03-06 收录
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The first silicon analogue of a carbonic ester, compound 2, and the novel cyclodisiloxane 4 have been synthesized by remarkably clean mono- and dioxygenation reactions of the stable siloxysilylene 1 with N2O (CO2) and O2, respectively. Ester 2 represents a unique donor-supported SiO complex with an intriguing thermal stability up to 200 °C. The addition of MeOH at the SiO bond in 2 furnishes the corresponding adduct 3.
创建时间：
2017-11-15
