Superexpanded Prussian-Blue Analogue with [Fe(CN)<sub>6</sub>]<sup>4-</sup>, [Nb<sub>6</sub>Cl<sub>12</sub>(CN)<sub>6</sub>]<sup>4-</sup>, and [Mn(<i>salen</i>)]<sup>+</sup> as Building Units
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资源简介：
A cluster-based 3D cyano-bridged trimetallic porous coordination polymer, [H3O]2[Fe(CN)6(Mn(salen))6Nb6Cl12(CN)6]·3H2O (1) with a superexpanded Prussian-blue-type structure built of [Nb6Cl12(CN)6]4-, [Fe(CN)6]4-, and [Mn(salen)]+ building units was synthesized and characterized. 1 shows overall ferromagnetic coupling and has a surface area of 55.4 m2/g.
创建时间：
2016-02-29
