Synthesis of Selenenium Ions: Isolation of Highly Conjugated, pH-Sensitive 4,4′-Bis(methylimino)-1,1′-binaphthylene-5-diselenenium(II) Triflate
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https://figshare.com/articles/dataset/Synthesis_of_Selenenium_Ions_Isolation_of_Highly_Conjugated_pH_Sensitive_4_4_Bis_methylimino_1_1_binaphthylene_5_diselenenium_II_Triflate/2339161
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资源简介：
The
isolation of novel selenenium cations, stabilized by only one intramolecularly
coordinating group (Se···N), is described. The electronic
nature of the cations has been probed by calculating natural bonding
orbital charges and Wiberg bond indices. [8-(Dimethylamino)-1-naphthyl]selenenyl(II)
triflate oxidizes in methanol via C–C coupling to give a novel
blue-colored 4,4′-bis(methylimino)-1,1′-binaphthylene-5-diselenenium(II)
triflate. The pH dependence of the color has been investigated.
创建时间：
2013-12-23
