Total Synthesis of the Proposed Structure for Spirofungin B: A Reassignment of the Stereochemistry
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https://figshare.com/articles/dataset/Total_Synthesis_of_the_Proposed_Structure_for_Spirofungin_B_A_Reassignment_of_the_Stereochemistry/3346156
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资源简介：
The total synthesis of the proposed structure for spirofungin B (2) is described. The data for the synthetic material did not compare with that
for the natural product leading to the conclusion that the structure 2 assigned for spirofungin B is incorrect. Analysis of the NMR data
reported for spirofungins A and B as well as related spiroketals allowed for the reassignment of the stereochemistry of spirofungin B to be
that corresponding to 15-epi-spirofungin A (27).
创建时间：
2016-05-07
