Synthesis of N‑Heterocyclic Carbene Gold Complexes Using Solution-Phase and Solid-State Protocols
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Several new phenolate complexes were prepared by reacting [Au(IPr)(OH)] (IPr = 1,3-bis(2,6-di-iso-propylphenyl)imidazol-2-ylidene) with phenols in solution. These complexes were also prepared by a new method. The precursor to the gold hydroxide [Au(IPr)Cl] was simply ground with KOH and the organic substrates. [Au(IPr)(R)] complexes that required heating in solution for extended periods of time were prepared using the grinding method in only minutes.
创建时间：
2016-02-19
