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Supporting data for ''Transition Metal-Catalyzed Functionalization, Anti-Markovnikov Oxidation and Difluorination. And Spectroscopic Characterization of Reactive Iron(IV)-oxo Corrole Intermediate''

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Figshare2022-09-26 更新2026-04-28 收录
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https://figshare.com/articles/dataset/Supporting_data_for_Transition_Metal-Catalyzed_Functionalization_Anti-Markovnikov_Oxidation_and_Difluorination_And_Spectroscopic_Characterization_of_Reactive_Iron_IV_-oxo_Corrole_Intermediate_/20970355
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File 1 is the supporting data for ''Iron (III)-Porphyrin-Triflate-Catalyzed Anti-Markovnikov Oxidation of Aliphatic Di- and Tri-Substituted Alkenes''. NMR data for substrates and products, as well as X-ray data for Fe-catalyst are included. File 2 is the supporting data for ''Characterization and Reactivity Study of Fe(IV)-oxo Corrole Cation Radical Species''. NMR, IR, UV, EPR and HR ESI-MS data for characterization of the reactive Fe-oxo intermediate and mechanistic studies are included. File 3 is the supporting data for ''Pd-Catalyzed 1,2-Di-fluorination and Di-functionalization of Unactivated Aliphatic Multi-Substituted Alkenes''. NMR data for substrates and products are included.
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2022-09-26
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