Cross-Dehydrocoupling of Amines and Silanes Catalyzed by Magnesocenophanes
收藏NIAID Data Ecosystem2026-03-12 收录
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The application of C[1]magnesocenophanes in dehydrocoupling catalysis is reported. Two new cycloalkylidene-bridged C[1]magnesocenophanes were synthesized and structurally characterized. These C[1]magnesocenophanes were used as catalysts in amine–borane dehydrocoupling and, more extensively, in amine–silane cross-dehydrocoupling. The substrate scope, involving different aliphatic, aromatic, and benzylic amines, was probed and the mechanism of this cross-dehydrocoupling catalysis was investigated.
创建时间：
2021-06-30
