Anthryl-Substituted 3‑Silylene-2-silaaziridine Obtained by Isomerization of Disilacyclopropanimine: An Exocyclic Silene Showing a Distinct Intramolecular Charge Transfer Transition
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https://figshare.com/articles/dataset/Anthryl_Substituted_3_Silylene_2_silaaziridine_Obtained_by_Isomerization_of_Disilacyclopropanimine_An_Exocyclic_Silene_Showing_a_Distinct_Intramolecular_Charge_Transfer_Transition/2393446
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资源简介：
An anthryl-substituted exocyclic
silene, 3-silylene-2-silaaziridine,
was synthesized by isomerization of the corresponding disilacyclopropanimine.
The UV–vis spectrum of the silene shows a distinct intramolecular
charge transfer (ICT) transition from the π orbital of the SiC
double bond to the π* orbital of the anthryl moiety. The relatively
high-lying π(SiC) orbital of the 3-silylene-2-silaaziridine
moiety and the low-lying π* orbital of the anthryl group would
be responsible for the distinct ICT band.
创建时间：
2013-07-24
