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Allylic Carbon–Carbon Double Bond Directed Pd-Catalyzed Oxidative ortho-Olefination of Arenes

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Figshare2016-02-21 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Allylic_Carbon_Carbon_Double_Bond_Directed_Pd_Catalyzed_Oxidative_i_ortho_i_Olefination_of_Arenes/2535100
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Pd-catalyzed selective ortho-olefination of arenes assisted by an allylic C–C double bond at room temperature using O2 as a terminal oxidant is described. A possible mechanism involving the initial coordination of allylic CC bond to Pd followed by selective o-C–H bond metalation is proposed.
创建时间:
2016-02-21
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