Investigation of the Reactivity of Hydroxyborate Salts with Group IV Metal Complexes: Synthesis and Structural Characterization of the Zirconium and Hafnium Ionic Complexes [PPN]+[Cp2MMe(OB(C6F5)3)]−
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https://figshare.com/articles/dataset/Investigation_of_the_Reactivity_of_Hydroxyborate_Salts_with_Group_IV_Metal_Complexes_Synthesis_and_Structural_Characterization_of_the_Zirconium_and_Hafnium_Ionic_Complexes_PPN_sup_sup_Cp_sub_2_sub_MMe_OB_C_sub_6_sub_F_sub_5_sub_sub_3_sub_sup_sup_/2621692数据链接链接失效反馈
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资源简介：
The syntheses of some novel fluorinated and nonfluorinated hydroxyborate salts, [Q]+[HOB(C6F5)3]− and [Q]+[HOBPh3]− ([Q]+ = aprotic cation), are reported. The reactivities of both salts with group IV metal complexes were compared. The reaction of [PPN]+[HOB(C6F5)3]− ([PPN]+ = bis(triphenylphosphoranylidene)ammonium) with Cp2ZrMe2 and Cp2HfMe2 resulted in the formation of the ionic complexes [PPN]+[Cp2ZrMe(OB(C6F5)3)]− and [PPN]+[Cp2HfMe(OB(C6F5)3)]− in high yields. These complexes were fully characterized, and the covalent characteristics of the M–O and B–O bonds were established by X-ray crystallographic structural determination.
创建时间：
2016-02-23
