Gold and Palladium Mediated Bimetallic Catalysis: Mechanistic Investigation through the Isolation of the Organogold(I) Intermediates
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https://figshare.com/articles/dataset/Gold_and_Palladium_Mediated_Bimetallic_Catalysis_Mechanistic_Investigation_through_the_Isolation_of_the_Organogold_I_Intermediates/9201944
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资源简介：
Au–Pd based
catalytic systems are a unique couple due to
the carbophilic Lewis acidity of Au and the redox properties of Pd.
To gain more insight into this bimetallic couple, a synthetic and
mechanistic investigation was conducted. As key substrates, ynamides
(N-alkynyl allyloxycarbamates and N-alkynyl ethyloxycarbamates) were used. Essential for the mechanistic
part was the isolation of the organogold(I) intermediate to validate
the proposed mechanism. In total, 18 polysubstituted oxazolones and
12 organogold(I) complexes were synthesized.
创建时间：
2019-07-12
