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Organically Templated Linear and Layered Iron Sulfates

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https://figshare.com/articles/dataset/Organically_Templated_Linear_and_Layered_Iron_Sulfates/3593691
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Linear and layered organically templated iron sulfates have been prepared under hydrothermal conditions. The linear iron sulfates, with the compositions [H3N(CH2)2NH3][FeF3(SO4)], I, [C(NH2)3]2[FeF(SO4)2], II, [H3N(CH2)2NH2(CH2)2NH3][FeF(SO4)2], III, and [H2N(CH2)4NH2][FeF3SO4], IV, possess the chain topologies found in tancoite, butlerite, and sideronatrite minerals. The layered sulfate V, with the composition [H3N(CH2)2NH3][Fe2F2(SO4)2(H2O)2], can be considered to be formed from butlerite-type chains and with a structure similar to that of the layered fluorophosphate, ULM-10. Whereas the linear chains show the presence of antiferromagnetic interactions, the layered iron sulfate exhibits metamagnetism.
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2016-08-17
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