Iodine(III)-Mediated Intermolecular Allylic Amination under Metal-Free Conditions
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https://figshare.com/articles/dataset/Iodine_III_Mediated_Intermolecular_Allylic_Amination_under_Metal_Free_Conditions/2526751
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资源简介：
A new approach to direct intermolecular allylic amination
has been
developed using metal-free conditions at room temperature. The reaction
employs a hypervalent iodine(III) reagent as an oxidant and bistosylimide
as a nitrogen source. A series of different allylic aminations are
presented with up to a 99% yield. Mechanistic studies including isotope
labeling and Hammett correlation suggest that depending on the substrate
structure two different mechanisms can be operating.
创建时间：
2016-02-21
