Improved One-Pot Synthesis of Mixed Methyl−Aryl Platinum(II) Diimine Complexes
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https://figshare.com/articles/dataset/Improved_One_Pot_Synthesis_of_Mixed_Methyl_Aryl_Platinum_II_Diimine_Complexes/3238651
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资源简介：
A general one-pot synthetic route for mixed methyl−aryl Pt(II) diimine complexes is described. Performing the
alkylation in neat Me2S instead of ether or THF greatly reduces
the amount of comproportionation products otherwise formed,
diminishes separation problems, and improves yields. Treatment
of the intermediate methyl−aryl complexes (Me2S)2Pt(Me)(Ar)
with diimines (N−N) furnishes the methyl−aryl Pt(II) diimine
complexes (N−N)Pt(Me)(Ar) in 76−84% yields. The Pt methyl−phenyl complex [p-Tol-NC(Me)C(Me)N-p-Tol]Pt(Me)(Ph)
has been characterized by X-ray diffraction.
创建时间：
2016-05-05
