β‑Octamethoxyporphycenes
收藏Figshare2016-02-18 更新2026-04-29 收录
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https://figshare.com/articles/dataset/_Octamethoxyporphycenes/2336446
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Porphycene with eight methoxy substituents at its β-positions was synthesized for the first time in three steps from 3,4-dimethoxypyrrole. The presence of methoxy groups increases its hydrophilicity as evident from their increased solubility in methanol. Among its metallo-derivatives, the Pd(II)-complex displays efficient singlet oxygen quantum yield (73%) and hence can be a potentially good photosensitizer for photo-oxidation, DNA cleavage, and photodynamic therapy (PDT).
创建时间:
2016-02-18



