A Novel Strategy for the Synthesis of 3-(N-Heteryl)pyrrole Derivatives
收藏Figshare2016-02-20 更新2026-04-29 收录
下载链接：
https://figshare.com/articles/dataset/A_Novel_Strategy_for_the_Synthesis_of_3_i_N_i_Heteryl_pyrrole_Derivatives/2503738
下载链接
链接失效反馈官方服务：
资源简介：
A flexible approach to unknown 1-(1H-pyrrol-3-yl)pyridinium salts with selective control of the substitution patterns, by the reaction of pyridinium ylides with 2H-azirines, is disclosed. 3-(Pyridinium-1-yl)pyrrolides, a new type of stable ylide, were prepared from these salts in high yields by treatment with base. Atmospheric-pressure hydrogenation of the ylides with Adams' catalyst lead to 1-(pyrrol-3-yl)piperidines in good yields.
创建时间：
2016-02-20
