Catalytic Isomerization of 2-Methyl-3-butenenitrile by Nickel Systems Using Bis-diphosphinoferrocene Ligands: Evidence for Hemilability
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The use of catalytic amounts of [Ni(COD)2] and a series of bis-diphosphinoferrocene ligands allows the catalytic isomerization of 2-methyl-3-butenenitrile to the linear 3-pentenenitrile, via allyl intermediates that display hemilability.
创建时间:
2007-11-19



