Synthesis of Highly Cis, Syndiotactic Polymers via Ring-Opening Metathesis Polymerization Using Ruthenium Metathesis Catalysts
收藏NIAID Data Ecosystem2026-03-07 收录
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The first example of ruthenium-mediated ring-opening metathesis polymerization generating highly cis, highly tactic polymers is reported. While the cis content varied from 62 to >95% depending on the monomer structure, many of the polymers synthesized displayed high tacticity (>95%). Polymerization of an enantiomerically pure 2,3-dicarboalkoxynorbornadiene revealed a syndiotactic microstructure.
创建时间：
2016-02-19
