Dimerization of β-Diketiminato Calcium Complexes through Dihapto-Acetylide Ligation
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https://figshare.com/articles/dataset/Dimerization_of_Diketiminato_Calcium_Complexes_through_Dihapto_Acetylide_Ligation/3296845
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资源简介：
The “selective” protonolysis of the β-diketiminato calcium derivative [Ca{(NDippCMe)2CH}{N(SiMe3)2}(THF)] (Dipp = C6H3iPr2-2,6) with a selection of terminal alkynes has produced a
series of dimeric acetylides [Ca{(NDippCMe)2CH}{μ-C⋮CR}]2, which have been characterized
in solution and in the solid state. The asymmetry of the Ca−C−Ca‘ bridges is subtly
dependent upon the extent of “side-on” (π-type) interaction between the acetylide unit and
the Ca‘ centers.
创建时间：
2016-05-06
