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Synthesis and Metalation of a Chiral, Pyridine-Strapped, Cyclic Bis(benzimidazole) Ligand<sup>†</sup>

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NIAID Data Ecosystem2026-03-06 收录
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Synthesis of a chiral, strapped, cyclic bis(benzimidazole) ligand is reported. This compound forms a stable, Jahn−Teller-distorted, octahedral Cu(II) complex in which the elongated axis is positioned within the main macrocycle. The C2-symmetric bis(benzimidazole) core adopts a highly ruffled conformation with the ortho-substituted benzene rings located anti relative to the pyridine-bearing strap.

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2016-05-07
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