Experimental and Computational Studies of the Diastereoselective Alkylations of 3‑Substituted γ‑Sultams
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https://figshare.com/articles/dataset/Experimental_and_Computational_Studies_of_the_Diastereoselective_Alkylations_of_3_Substituted_Sultams/2219989
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资源简介：
We
report that chiral 3-substituted γ-sultam α-carbanions
undergo diastereoselective alkylation reactions with alkyl halides
to predominantly produce trans-3,5-disubstituted
γ-sultam products. Quantum mechanical calculations provided
a stereoelectronic rationale for the observed diastereoselectivity.
创建时间：
2015-01-02
