Experimental and Computational Studies of the Diastereoselective Alkylations of 3‑Substituted γ‑Sultams
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We report that chiral 3-substituted γ-sultam α-carbanions undergo diastereoselective alkylation reactions with alkyl halides to predominantly produce trans-3,5-disubstituted γ-sultam products. Quantum mechanical calculations provided a stereoelectronic rationale for the observed diastereoselectivity.
创建时间：
2015-01-02
