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Application of the Dimensional Reduction Formalism to Pb12[Li2(P2O7)2(P4O13)2](P4O13): a Phosphate Containing Three Types of Isolated P–O Groups

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Figshare2016-07-26 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Application_of_the_Dimensional_Reduction_Formalism_to_Pb_sub_12_sub_Li_sub_2_sub_P_sub_2_sub_O_sub_7_sub_sub_2_sub_P_sub_4_sub_O_sub_13_sub_sub_2_sub_P_sub_4_sub_O_sub_13_sub_a_Phosphate_Containing_Three_Types_of_Isolated_P_O_Groups/3479342
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A new phosphate, Pb12[Li2(P2O7)2(P4O13)2]­(P4O13), containing three types of isolated polyphosphate anionic groups [P2O7], and two types of [P4O13] has been successfully synthesized by using Li2O as dimensional reduction agent to dismantle Pb3P4O13. The isolation of [P2O7] and two types of [P4O13] with different symmetries in the title compound mainly benefits from the large number and flexible coordination of the Pb2+ cations.
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2016-07-26
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