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Electrophilic Reactivities of Vinyl p‑Quinone Methides

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Figshare2020-03-02 更新2026-04-28 收录
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https://figshare.com/articles/dataset/Electrophilic_Reactivities_of_Vinyl_i_p_i_Quinone_Methides/11919522
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The electrophilic reactivity of a series of 8-arylated vinyl p-quinone methides (pVQMs) was determined by analyzing the kinetics of their reactions with carbanions in DMSO at 20 °C according to the linear free energy relationship log k = sN(N + E). The electrophilicity parameters E for pVQMs were used to successfully predict Michael-additions with structurally diverse C-, N-, S-, and H-nucleophiles.
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2020-03-02
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