Secondary Carbocations in the Biosynthesis of Pupukeanane Sesquiterpenes
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https://figshare.com/articles/dataset/Secondary_Carbocations_in_the_Biosynthesis_of_Pupukeanane_Sesquiterpenes/7140641
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The results of quantum chemical calculations on putative biosynthetic carbocation cyclization/rearrangements leading to pupukeanane and related sesquiterpenes indicate that a secondary carbocation proposed as an intermediate is not a minimum on the potential energy surface and instead resides in a region of the potential energy surface associated with a plateau containing multiple exit channels.
创建时间：
2018-09-27
