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Rapid Access to Polyprenylated Phloroglucinols via Alkylative Dearomatization−Annulation: Total Synthesis of (±)-Clusianone

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NIAID Data Ecosystem2026-03-06 收录
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A concise approach to the bicyclo[3.3.1]nonane framework of the polyprenylated phloroglucinol natural products utilizing a tandem alkylative dearomatization−annulation sequence is described. Syntheses of (±)-clusianone and a complex adamantane framework have been achieved using the developed methodology.

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2007-10-24
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