A Unique Cyanide-Bridged Three-Dimensional (3-D) Copper(II)−Copper(I) Mixed-Valence Polymer Containing 1-D Water Tapes with Cyclic Pentamer Units
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https://figshare.com/articles/dataset/A_Unique_Cyanide_Bridged_Three_Dimensional_3_D_Copper_II_Copper_I_Mixed_Valence_Polymer_Containing_1_D_Water_Tapes_with_Cyclic_Pentamer_Units/3286021
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资源简介：
A unique cyano-bridged copper(II)−copper(I) mixed-valence polymer, {[Cu3(CN)4(H2O)3](H2O)2}n (1), has been prepared and
structurally determined by X-ray diffraction. The cyanide anions
with (μ2,η2) and (μ3,η2) bridging modes connect the copper centers
into a complicated zeolite-like 3-D network. Of further interest,
coordinated and lattice water molecules in this structure form 1-D
hydrogen-bonded water tapes consisting of linked cyclic pentamer
clusters.
创建时间：
2005-05-16
