Spin-Hamiltonian and quadrupole doublet parameters used in the 4.2 K Mössbauer simulations.
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Parameters: δ –isomeric shift, η – asymmetry parameter, ΔEQ –quadrupole splitting; Γ – line width; A- hyperfine constant.The diferric and mixed-valence parameters were determined from as-isolated RIC, while the diferrous parameters were determined from reduced RIC (data not shown).
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2015-12-02
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