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Synthesis and Electronic Properties of Isotruxene-Derived Star-Shaped Ladder-Type Oligophenylenes: Bandgap Tuning with Two-Dimensional Conjugation

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NIAID Data Ecosystem2026-03-06 收录
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The synthesis of star-shaped ladder-type oligophenylenes Sn (n = 4, 7, 10, 13, and 16), where n is the number of π-conjugated phenylene rings, is reported. The two-dimensional conjugation interactions in Sn result in a lower bandgap for S16 than the currently known ladder-type poly(p-phenylene)s (LPPPs).

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2016-02-25
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