Direct Synthesis of Alkenyl Boronic Esters from Unfunctionalized Alkenes: A Boryl-Heck Reaction
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https://figshare.com/articles/dataset/Direct_Synthesis_of_Alkenyl_Boronic_Esters_from_Unfunctionalized_Alkenes_A_Boryl_Heck_Reaction/3189031
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资源简介：
We
report the first example of a boryl-Heck reaction using an electrophilic
boron reagent. This palladium-catalyzed process allows for the conversion
of terminal alkenes to trans-alkenyl boronic esters
using commercially available catecholchloroborane (catBCl). In situ transesterification allows for rapid access to a
variety of boronic esters, amides, and other alkenyl boron adducts.
创建时间：
2016-04-29
